Aurophilicity under pressure: a combined crystallographic and in situ spectroscopic study.
نویسندگان
چکیده
High pressure crystallographic studies on [1,4-C6H4{PPh2(AuCl)}2] (1) reveal the largest pressure-induced contraction of an aurophilic interaction observed for any Au(i) complex; Hirshfeld surface analysis and Raman spectroscopy reveal the presence of several types of intermolecular interaction, which play an important role in the behaviour of 1 as a function of pressure.
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ورودعنوان ژورنال:
- Chemical communications
دوره 52 41 شماره
صفحات -
تاریخ انتشار 2016